A Toilet Cleaner Anti-bacterial Ceramics AM15
      for the 21st Century

The oligodynamic effect in layman's terms actually means the antibacterial function that some metal ions have. The first microbiological application was reported by Carl von Nageil in Switzerland in 1893, indicating that it was successful in getting rid of algae from water tanks. However, even in ancient times, people were aware of the effect from their own experience; water kept its freshness much longer if silverware was immersed in it. It was said that when the kings of yore went on a military expedition they always immersed silverware in the water to prevent it from becoming contaminated. In addition to silver ion some other metal ions also have the following effect ( in order of antibacterial intensity).
Hg>Ag>Cu>Zn>Fe>Pb>Bi
Silver ion is thought to be the most useful not only because of the excellent antibacterial effect even if added to water in small amounts, but also because it dose not have an adverse effect on the human body.
Sumitomo Osaka Cement Co., Ltd.have studied the properties of silver ion over a number of years and finally developed the AM15 antibacterial additive to be mixed in glaze of ceramic sanitary ware. We are proud of the so called "Antibacterial Toilet" which has been very successfully marketed in Japan to the extent that it now accounts for major share of the Japanese sanitary ware market.






Features






AM15 (ceramic powder) should be mixed in the ratio of 1~3wt% of glaze. The merits of AM15 are
•Antibacterial effect of silver ion Contained in AM15 which is harmless.
•When sintered in glaze at high temperatures remains unaffected as the eoxidization andevaporation reaction of silver ion is controlled.
•Bacteria multi plus slowly on the surface of the glaze.
•The antibacterial effect lasts semi-permanently under normal conditions.






Keeping clean effects on glaze with AM15






1) Stall type toilet (Photo 1)
Tests were conducted in a public lavatory for two months period. One stall type toilet was "treated" with AM15 the other not. The toilets were not cleaned around the traps during the period resulting in discoloration and build up of urine stone on the "non treated" type and little discoloration or urine stone on the AM15 type.




2) Wash basins (Photo 2 and 3)
A test conducted on a wash basin in a private house indicated that if the wash basin was not cleaned for a month brown staining would appear on the untreated surface but little staining on the treated surface.







Examination of Antibacterial activity






The "Film Adherence Method" which is the Japanese self- imposed standard lab test method for antibacterial products was used to measure the antibacterial activity of glaze treated with AM15. The resul was shown in Table 1.

Table 1: Antibacterial Activity of Glaze Mixed with AM15
Bacteria
ItemsTested
Initial cell count(cfu.)
24h.later cell count(cfu.)
Escherichia coli
without AM-15
5.2×105
5.2×106
with AM-15
5.2×105
10>
Staphylococcus aureus
without AM-15
3.6×105
1.6×106
with AM-15
3.6×105
10>








Results of safety tests conducted on AM15






•LD50 (Acute oral toxicity)
•Primary skin irritation
•Mutagenicity
•Skin sensitization
2000mg/kg<
week
negative
negative



Sumitomo Osaka Cement Co., Ltd.
NANO MATERIALS BUSINESS GROUP SALES TEAM
6-28, Rokubancho, Chiyoda-ku, Tokyo 102-8465, Japan
Phone +81-3-5211-4799  Fax +81-3-3221-5692
e-mail: materials_sales@socnb.com
URL: www://socnb.com

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TEL: +1-201-461-0100 FAX: +1-201-461-7001 e-mail : materials_sales@socnb.com